Vapor growth of carbon micro-coils by the Ni catalyzed pyrolysis of acetylene using rotating substrate

Vapor growth of carbon micro-coils by the Ni catalyzed pyrolysis of acetylene using rotating substrate
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DOI:
10.1016/s0167-577x(99)00220-7
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发表时间:
2000-03
期刊:
影响因子:
3
通讯作者:
W. In-Hwang;H. Yanagida;S. Motojima
W. In-Hwang;H. Yanagida;S. Motojima
中科院分区:
材料科学3区
文献类型:
--
作者:
W. In-Hwang;H. Yanagida;S. Motojima

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采用旋转衬底,在770℃下用镍催化乙炔裂解制得了碳微线圈。考察了转速对碳线圈的成品率、形貌和手性的影响。由于衬底转速为180rpm,线圈成品率下降了35%-50%,得到了不规则的碳线圈,而不旋转的情况下得到了规则的线圈。不能得到具有选择性手性的碳线圈。
Carbon micro-coils were obtained by the Ni-catalyzed pyrolysis of acetylene at 770°C using a rotating substrate. The effects of the rotating speed on the coil yield, morphology and chirality of the grown carbon coils were examined. The coil yield decreased by 35–50% due to the substrate rotation of 180 rpm and irregular carbon coils were obtained, while regular coils were obtained without rotation. The carbon coils with a selective chirality could not be obtained.