In situ Seamless Magnetic Measurements for Solid-State Electrochemical Processes in Prussian Blue Analogues

In situ Seamless Magnetic Measurements for Solid-State Electrochemical Processes in Prussian Blue Analogues
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普鲁士蓝类似物固态电化学过程的原位无缝磁测量

DOI：
10.1002/ange.201301084
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发表时间：
2013
期刊：
Angew. Chem. Int. Ed.
影响因子：
--
通讯作者：
and K. Awaga,
and K. Awaga,
中科院分区：
--
文献类型：
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作者：
T. Yamada;K. Morita;H. Wang;K. Kume;H. Yoshikawa;and K. Awaga,

文献摘要

相似文献

无缝观测：已开发出固态电化学环境中的磁性测量，并将其应用于混合价铬普鲁士蓝类似物(PBA)亚铁磁体。将含有PBA作为正极活性物质的电池插入到SQUID中，控制了电池放电过程中PBA的还原。磁性变化可以用氧化还原引起的铬离子的自旋变化来解释。
Seamless observation: Magnetic measurements in a solid‐state electrochemical environment have been developed and applied to a mixed‐valent chromium Prussian blue analogue (PBA) ferrimagnet. Battery cells containing PBA as a cathode active material were inserted into a SQUID and the PBA reduction during battery discharge was controlled. Magnetic changes were revealed that can be understood by the redox‐induced spin changes of the Cr ions.