The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts.
The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts.
复制标题
外围联吡啶配体对Ru/Pd催化剂光催化制氢活性的影响。
作者：
Gurmeet Singh Bindra;M. Schulz;Avishek Paul;Suraj Soman;R. Groarke;Jane L Inglis;M. Pryce;W. R. Browne;S. Rau;B. MacLean;J. Vos
报道了一种吡嗪桥接钌/钯双金属光催化剂，其外围配体为4,4'-二羧基乙基-2,2'-联吡啶，EtOOC-RuPd及其2,2'-联吡啶类似物。在可见光照射下，EtOOC-RuPd催化氢气的产生，而复合物RuPd则没有。
A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.