Ruthenium Vinylidene Complexes Generated by Selective 1,2-Migration of P- and S-Substituents: Synthesis, Structures, and Dichromism Arising from an Intramolecular CH···O Hydrogen Bond

Ruthenium Vinylidene Complexes Generated by Selective 1,2-Migration of P- and S-Substituents: Synthesis, Structures, and Dichromism Arising from an Intramolecular CH···O Hydrogen Bond
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P-和S-取代基选择性1,2-迁移生成的亚乙烯基钌配合物:合成、结构和分子内CH·O氢键产生的二色性

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发表时间:
2020
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影响因子:
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通讯作者:
Y. Ishii
Y. Ishii
中科院分区:
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文献类型:
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作者:
Takuya Kuwabara;Y. Aoki;Kousuke Sakajiri;Kazuki Deguchi;Shuhei Takamori;Ai Hamano;K. Takano;H. Houjou;Y. Ishii

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磷和硫取代的内炔在钌中心的亚乙烯基重排的研究揭示了P-和S-取代基的选择性1,2-迁移和意想不到的结果。
Investigation of the vinylidene rearrangement of phosphorus- and sulfur-substituted internal alkynes at a ruthenium center unveiled selective 1,2-migration of P- and S-substituents and unexpected d...