Total synthesis of (±)-aspercyclide A and its C19 methyl ether

Total synthesis of (±)-aspercyclide A and its C19 methyl ether
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DOI:
10.1039/b923528k
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发表时间:
2010-01-01
影响因子:
4.9
通讯作者:
Spivey, Alan C.
Spivey, Alan C.
中科院分区:
化学2区
文献类型:
--
作者:
Carr, James L.;Offermann, Daniel A.;Spivey, Alan C.

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本文报道了(+/-)-半精环内酯A(1)及其C19甲醚(15 a)的全合成,其特征是Heck-Mizoroki大环化反应生成11元(E)-苯乙烯基联芳醚内酯核。
The total syntheses of (+/-)-aspercyclide A (1) and its C19 methyl ether (15a) featuring Heck-Mizoroki macrocyclisation to form the 11-membered (E)-styrenyl biaryl ether lactone core are described.