A new family of supramolecular multiferrocenyl rhomboids: Synthesis, characterization, and their electrochemical behavior

A new family of supramolecular multiferrocenyl rhomboids: Synthesis, characterization, and their electrochemical behavior
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DOI:
10.1016/j.cclet.2013.03.055
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发表时间:
2013-06
影响因子:
9.1
通讯作者:
Jiang-Kun Ou-Yang;Li-Jun Chen;Lin Xu;Cui-Hong Wang;Hai‐Bo Yang
Jiang-Kun Ou-Yang;Li-Jun Chen;Lin Xu;Cui-Hong Wang;Hai‐Bo Yang
中科院分区:
化学1区
文献类型:
--
作者:
Jiang-Kun Ou-Yang;Li-Jun Chen;Lin Xu;Cui-Hong Wang;Hai‐Bo Yang

文献摘要

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通过配位驱动的自组装,以新设计的60°二茂铁基给体前体1为原料,成功构建了两个新型的超分子多二茂铁基菱形化合物5和6.通过多核NMR(1H和31 P)、CSI-TOF-MS和PM 6半经验分子模拟对所有多二茂铁菱形化合物的结构进行了表征,并研究了它们的电化学行为。
Two novel, supramolecular, multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60° ferrocenyl donor precursor 1via coordination-driven self-assembly. The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR (1H and31P), CSI–TOF-MS, and PM6 semi-empirical molecular simulation, and their electrochemical behaviors have been investigated.