A RIGOROUS DERIVATION OF THE CHEMICAL MASTER EQUATION
A RIGOROUS DERIVATION OF THE CHEMICAL MASTER EQUATION
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DOI：
10.1016/0378-4371(92)90283-v
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发表时间：
1992-09-01
期刊：
影响因子：
3.3
通讯作者：
GILLESPIE, DT
中科院分区：
文献类型：
--
作者：
GILLESPIE, DT
人们普遍认为，化学主方程没有严格的微观物理基础，因此没有先验的有效性。这一观点在这里受到了挑战，因为这些论点试图证明，化学主方程对于任何保持良好搅拌和热平衡的气相化学体系都是准确的。
It is widely believed that the chemical master equation has no rigorous microphysical basis, and hence no a priori claim to validity. This view is challenged here through arguments purporting to show that the chemical master equation is exact for any gas-phase chemical system that is kept well stirred and thermally equilibrated.