A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
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DOI：
10.1021/om8000108
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发表时间：
2008-02
期刊：
影响因子：
2.8
通讯作者：
Ajdin Kavara;Kandarpa D. Cousineau;Ahleah D. Rohr;J. Kampf;M. Holl
中科院分区：
文献类型：
--
作者：
Ajdin Kavara;Kandarpa D. Cousineau;Ahleah D. Rohr;J. Kampf;M. Holl
烯丙基CH键的活化和跨C → C双键的加成都在烯烃与锡烯/苯基碘试剂的反应中观察到。这些产物中的每一种的相对量对烯烃和芳基卤化物的空间体积敏感。
Allylic CH bond activation and addition across the C═C double bond are both observed in the reactions of alkenes with a stannylene/phenyl iodide reagent. The relative amounts of each of these products are sensitive to the steric bulk of the alkene and of the aryl halide.