Do amino acids equilibrate in hydrothermal fluids

Do amino acids equilibrate in hydrothermal fluids
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氨基酸在热液中平衡吗

DOI:
10.1016/0016-7037(90)90450-y
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发表时间:
1990
期刊:
影响因子:
--
通讯作者:
E. Shock
E. Shock
中科院分区:
--
文献类型:
--
作者:
E. Shock

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对米勒和Bada(1988年)报告的数据进行的分析表明,在250°C和265大气压下进行的含水热解实验结束时,三种含水氨基酸接近亚稳平衡浓度。在系统完全稳定之前终止实验,但这些结果表明氨基酸在水热条件下在水溶液中平衡。虽然无意的,这可能是第一次实验证实,亚稳态平衡的特点,在热液流体中的有机化合物的相互作用。
Analysis of data reported by Miller and Bada (1988) shows that three aqueous amino acids approached metastable equilibrium concentrations toward the end of hydrous pyrolysis experiments conducted at 250°C and 265 atm. The experiments were terminated before the system had stabilized completely, but these results indicate that amino acids equilibrate in aqueous solution at hydrothermal conditions. Although unintentional, this may be the first experimental confirmation that metastable equilibria characterize the interaction of organic compounds in hydrothermal fluids.