Thermal production and reactions of organic ions at atmospheric pressure
Thermal production and reactions of organic ions at atmospheric pressure
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DOI：
10.1002/anie.200600660
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Cooks, R. Graham
中科院分区：
文献类型：
--
作者：
Chen, Hao;Zheng Ouyang;Cooks, R. Graham
（图所示）加热：各种有机盐，包括离子液体和过渡金属盐，在大气压下发生热电离。这种热方法允许研究离子-分子反应；例如，当热生成的吡啶离子与固体赖氨酸在环境条件下发生反应时，d -赖氨酸的快速选择性脱附和衍生化发生（见图）。
(Figure Presented) The heat is on: Thermal ionization of a variety of organic salts including ionic liquids and transition-metal salts occurs at atmospheric pressure. This thermal method allows for the study of ion-molecule reactions; for example, the fast selective desorption and derivatization of D-lysine occurs when thermally generated pyrylium ions react with solid lysine under ambient conditions (see picture).