Observation of hysteretic bistability in [Co(III)Cp(2)](+)[Fe(III)I(4)](-).

Observation of hysteretic bistability in [Co(III)Cp(2)](+)[Fe(III)I(4)](-).
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观察 [Co(III)Cp(2)]( )[Fe(III)I(4)](-) 的滞后双稳态。

DOI:
10.1021/ic049000g
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发表时间:
2004
影响因子:
4.6
通讯作者:
Joel S A Miller
Joel S A Miller
中科院分区:
化学2区
文献类型:
--
作者:
Jesse M. Migliori;W. Reiff;A. Arif;Joel S A Miller

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由 FeI(2) 和 CoCp(2) 与碘双重氧化制备的 [Co(III)Cp(2)](+)[Fe(III)I(4)](-) (Cp = 环戊二烯基) 在 134 至 164 K 之间的磁化率中表现出 30 摄氏度的热滞,这是由于在冷却。
[Co(III)Cp(2)](+)[Fe(III)I(4)](-) (Cp = cyclopentadienyl) prepared by the double oxidation of FeI(2) and CoCp(2) with iodine exhibits a 30 degrees C thermal hysteresis in magnetic susceptibility between 134 and 164 K that is attributed to a phase transition to a disordered triclinic unit cell from an ordered monoclinic unit cell upon cooling.