Phosphine Oxidation with Water and Ferrocenium(III) Cation Induced by Visible-Light Irradiation
Phosphine Oxidation with Water and Ferrocenium(III) Cation Induced by Visible-Light Irradiation
复制标题
可见光照射诱导水和二茂铁(III)阳离子氧化磷化氢
DOI：
10.1002/chem.201805129
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发表时间：
2018
期刊：
影响因子：
--
通讯作者：
Yoshiaki Nishibayashi
中科院分区：
文献类型：
--
作者：
Yoshiaki Tanabe;Kazunari Nakajima;Yoshiaki Nishibayashi
在可见光照射下，以2,6 -鲁替丁为质子受体，以水和二铁（III）阳离子为氧原子源和氧化试剂，在乙腈中实现了磷化氢的化学计量氧化。该反应需要光照，在光照下观察到二茂铁（III）阳离子的乙腈溶液的荧光。
Stoichiometric oxidation of phosphines with water and ferrocenium(III) cation as the oxygen atom source and the oxidizing reagent, respectively, was achieved in acetonitrile under visible‐light irradiation by using 2,6‐lutidine as the proton acceptor. The reaction required light irradiation, under which fluorescence was observed for the acetonitrile solution of the ferrocenium(III) cation.