Solubility Limits in Binary (Ca,Mn) Chalcogenides

Solubility Limits in Binary (Ca,Mn) Chalcogenides
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DOI:
10.1111/j.1151-2916.1979.tb12743.x
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发表时间:
1979-11
影响因子:
3.9
通讯作者:
C. Leung;L. H. Vlack
C. Leung;L. H. Vlack
中科院分区:
材料科学2区
文献类型:
--
作者:
C. Leung;L. H. Vlack

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在CaS-MnS、CaSe-MnSe和CaTe-MnTe体系中,固溶度逐渐降低。在CaS-MnS中,全固态结晶度从1150° C延伸到1500°C,液相线最低点。对于CaSe-MnSe,该范围为1070°至1340°C。CaTe和立方MnTe之间的固体可熔性间隙在1050°C下作为共晶截断液相线。固溶体严格遵循Vegard定律。
Solid solubilities progressively decrease in the systems CaS-MnS, CaSe-MnSe, and CaTe-MnTe. In CaS-MnS, full solid miscibility extends from 1150° to 1500°C, the liquidus minimum. With CaSe-MnSe, this range is 1070° to 1340°C. The solid miscibility gap between CaTe and cubic MnTe intercepts the liquidus as a eutectic at 1050°C. The solid solutions follow Vegard's law closely.