Dynamic coordination polymers with 4,4'-oxybis(benzoate): reversible transformations of nano- and nonporous coordination frameworks responding to present solvents.
Dynamic coordination polymers with 4,4'-oxybis(benzoate): reversible transformations of nano- and nonporous coordination frameworks responding to present solvents.
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DOI：
10.1021/ic0496166
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发表时间：
2004-10
影响因子：
4.6
通讯作者：
M. Kondo;Y. Irie;Y. Shimizu;M. Miyazawa;H. Kawaguchi;A. Nakamura;Tetsuyoshi Naito;K. Maeda;
中科院分区：
文献类型：
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作者：
M. Kondo;Y. Irie;Y. Shimizu;M. Miyazawa;H. Kawaguchi;A. Nakamura;Tetsuyoshi Naito;K. Maeda;
在具有 4,4'-氧双（苯甲酸酯）（oba）的锌（II）配位聚合物中发现了从无孔骨架可逆构建纳米多孔骨架的过程。 [Zn(2)(oba)(2)(dmf)(2)].2DMF (1)具有1 nm尺度的通道，在失去开放框架的情况下转变为无孔配位聚合物[Zn(oba)(H(2)O)] (2)。用 DMF 处理化合物 2 可逆地产生纳米多孔化合物 1。
Reversible construction of a nanoporous framework from a nonporous framework has been found in the zinc(II) coordination polymer with 4,4'-oxybis(benzoate) (oba). [Zn(2)(oba)(2)(dmf)(2)].2DMF (1), which has 1 nm scale channels, transforms to the nonporous coordination polymer [Zn(oba)(H(2)O)] (2) with the loss of the open framework. Compound 2 on treatment with DMF reversibly yields nanoporous compound 1.