CHARACTERIZATION OF COATINGS CREATED ON SELECTED TITANIUM ALLOYS BY PLASMA ELECTROLYTIC OXIDATION

CHARACTERIZATION OF COATINGS CREATED ON SELECTED TITANIUM ALLOYS BY PLASMA ELECTROLYTIC OXIDATION
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DOI:
10.1515/adms-2016-0001
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发表时间:
2016-03-01
影响因子:
1.3
通讯作者:
Malorny, W.
Malorny, W.
中科院分区:
其他
文献类型:
--
作者:
Rokosz, K.;Hryniewicz, T.;Malorny, W.

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本文介绍了纯铌和钛合金(NiTi和Ti6 Al 4V)在含有300 g和600 g硝酸铜的1升浓磷酸溶液中,450 V,3分钟等离子体电解氧化得到的涂层的SEM和EDS结果。所获得的涂层是多孔的,并且主要由钛和铜中的磷组成。对于每个涂层,计算Cu/P比率。对于在含有600 g Cu(NO3)(2)在1 dm(3)H3 PO 4中的电解液中氧化的铌和Ti6 Al 4V合金,发现该系数的最大值等于0.22(wt%)。|0.11(at%)。对于在电解液中被PEO氧化的NiTi和Ti6 Al 4V合金,记录了Cu/P比的最小值,该电解液由300 g硝酸铜在1 dm 3的浓磷酸中组成,并且等于0.12(wt%)。|0.06(at%)。对于NiTi记录该比率的中间值,其等于0.16(重量%)。|0.08(at%)。
The SEM and EDS results of coatings obtained on pure niobium and titanium alloys (NiTi and Ti6Al4V) by Plasma Electrolytic Oxidation in the electrolytes containing of 300 g and 600 g copper nitrate in 1 litre of concentrated phosphoric acid at 450 V for 3 minutes, are presented. The obtained coatings are porous and consist mainly of phosphorus within titanium and copper. For each coating, the Cu/P ratios were calculated. The maximum of that coefficient was found for niobium and Ti6Al4V alloy oxidised in the electrolyte containing 600 g of Cu(NO3)(2) in 1 dm(3) of H3PO4 and equaling to 0.22 (wt%) | 0.11 (at%). The minimum of Cu/P ratio was recorded for NiTi and Ti6Al4V alloys oxidised by PEO in electrolyte consisting of 300 g of copper nitrate in 1 dm3 of concentrated phosphoric acid and equals to 0.12 (wt%) | 0.06 (at%). The middle value of that ratio was recorded for NiTi and it equals to 0.16 (wt%) | 0.08 (at%).