Theory of square, rectangular, and microband electrodes through explicit GPU simulation

Theory of square, rectangular, and microband electrodes through explicit GPU simulation
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DOI:
10.1016/j.jelechem.2010.05.007
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发表时间:
2010-07-01
影响因子:
4.5
通讯作者:
Compton, Richard G.
Compton, Richard G.
中科院分区:
化学3区
文献类型:
--
作者:
Cutress, Ian J.;Compton, Richard G.

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近年来,由于提高了电流密度,易于制造和可用的理论,微带电极在电化学中的使用已经扩大。本文通过显式三维有限差分CPU模拟,模拟质量传输到正方形和矩形(有限带)微电极,并量化有限带在任何给定的长宽比的响应,包括验证计时电流响应方程。此外,强调了利用现代计算硬件的显式模拟的力量。(C)2010 Elsevier B.V.保留所有权利。
The use of microband electrodes in electrochemistry has expanded in recent years due to enhanced current densities, ease of fabrication, and available theory. This paper, through explicit three-dimensional finite difference CPU simulation, simulates mass transport to square and rectangular (finite band) micro-electrodes and quantifies the response of a finite band at any given length to width ratio, including the validation of an equation for the chronoamperometric response. In addition, the power of explicit simulations harnessed to modern computing hardware is emphasised. (C) 2010 Elsevier B.V. All rights reserved.