Copper(I) mediated living radical polymerisation in an ionic liquid
Copper(I) mediated living radical polymerisation in an ionic liquid
复制标题
DOI：
10.1039/b003335i
复制
发表时间：
2000-01-01
影响因子：
4.9
通讯作者：
Seddon, KR
中科院分区：
文献类型：
--
作者：
Carmichael, AJ;Haddleton, DM;Seddon, KR
1-丁基-3-甲基咪唑鎓六氟磷酸盐是一种室温离子液体，已被用作甲基丙烯酸甲酯的铜（I）介导的活性自由基聚合的溶剂;反应速率得到提高，并获得易于从催化剂分离的窄多分散性聚合物。
1-Butyl-3-methylimidazolium hexafluorophosphate, a room temperature ionic liquid, has been used as solvent for the copper(I) mediated living radical polymerisation of methyl methacrylate; the rate of reaction is enhanced and narrow polydispersity polymers are obtained which are easily isolated from the catalyst.