A new luminescent 3D metal-organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer.
A new luminescent 3D metal-organic framework possessing a rare (3,5)-connected net which can be transformed from a 2D double layer.
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DOI：
10.1039/b815935a
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发表时间：
2009-02
影响因子：
4
通讯作者：
Haiyan He;Fangna Dai;Daofeng Sun
中科院分区：
文献类型：
--
作者：
Haiyan He;Fangna Dai;Daofeng Sun
采用非平面二羧酸配体，合成了一种具有罕见的（3,5）连接网的新型三维金属有机骨架Zn(TBDC(1))(1/2)(TBDC(2))(1/2) ()；通过热释放配位的水和dmf分子，可以在二维双层中形成配合物，同时发生发光增强的变化。
Applying a nonplanar dicarboxylate ligand, a new 3D metal-organic framework, Zn(TBDC(1))(1/2)(TBDC(2))(1/2) (), possessing a rare (3,5)-connected net has been synthesized and characterized; complex can be formed from a 2D double layer by thermally liberating the coordinated water and dmf molecules, simultaneous with luminescence-increased changes.