Cyclometalated Iridium Complexes as Highly Active Catalysts for the Hydrogenation of Imines

Cyclometalated Iridium Complexes as Highly Active Catalysts for the Hydrogenation of Imines
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环金属化铱配合物作为亚胺加氢的高活性催化剂

DOI:
10.1055/s-0033-1340086
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发表时间:
2013
期刊:
影响因子:
2
通讯作者:
Xiao J
Xiao J
中科院分区:
化学4区
文献类型:
--
作者:
Xiao J

文献摘要

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开发了一种用于亚胺高效加氢的环金属化Ir催化剂。由于催化剂的负载量很低(低至0.005%),在温和的条件下,一系列底物在短的反应时间内获得了良好到极好的产率,为制备胺提供了一种简单、高效的方案。
A robust cyclometalated iridium catalyst has been developed for highly effective hydrogenation of imines. With very low catalyst loading (down to 0.005%), good to excellent yields have been achieved for a range of substrates in a short reaction time under mild conditions, providing an easy, efficient protocol for making amines.