Multiple Bragg Diffractions with Different Wavelengths and Polarizations Composed of Liquid Crystal/Polymer Periodic Phases
Multiple Bragg Diffractions with Different Wavelengths and Polarizations Composed of Liquid Crystal/Polymer Periodic Phases
复制标题
DOI：
10.1021/acsomega.7b01149
复制
发表时间：
2017-09
期刊：
影响因子：
4.1
通讯作者：
H. Kakiuchida;A. Ogiwara;A. Matsuyama
中科院分区：
文献类型：
--
作者：
H. Kakiuchida;A. Ogiwara;A. Matsuyama
We first fabricated holographic polymer-dispersed liquid crystals (HPDLCs) that produce multiple Bragg diffractions with different polarization states for every angle of incidence, through a photopolymerization-induced phase separation by one-time interferential exposure. The polarizations of the Bragg diffractions were well-controlled at individual wavelengths in the fabrication process by the compositional ratio of LCs to monomers. The raw mixtures of extremely low-functionality monomers having very different viscosities were used to reduce the domain size in phase separation and subsequently to form elaborate periodic structures of the LC and polymer phases. A cross-linker (1-vinyl-2-pyrrolidione) and a prepolymer with urethane groups were employed to strengthen the polymer network. Note that the diffractions of our HPDLCs are regarded as not purely but mostly Bragg type, according to the evaluation with the established criteria. The devices, which are monolithic but versatile in diffractive behaviors, have advantages of simple manufacturing and handling.
