Palladium chloride-catalyzed reductive cleavage of benzylic acetal, ketal and ether compounds with triethylsilane
Palladium chloride-catalyzed reductive cleavage of benzylic acetal, ketal and ether compounds with triethylsilane
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氯化钯催化三乙基硅烷对苄基缩醛、缩酮和醚化合物的还原裂解
DOI：
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发表时间：
2011
期刊：
影响因子：
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通讯作者：
R. Zadmard
中科院分区：
文献类型：
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作者：
M. Mirza‐Aghayan;R. Boukherroub;M. Rahimifard;R. Zadmard
描述了用三乙基硅烷和催化量的氯化钯将苯缩醛、缩醛和醚类化合物还原裂解为相应的烷烃。还原反应在温和的条件下进行，反应时间短，相应的烷烃化合物收率高。
Reductive cleavage of benzylic acetal, ketal and ether compounds to the corresponding alkanes using triethylsilane and a catalytic amount of palladium(II) chloride is described. The reductive reaction took place under mild conditions, affording high yields of the corresponding alkane compounds in short reaction times.