Secondary phosphine oxides as pre-ligands for nanoparticle stabilization
Secondary phosphine oxides as pre-ligands for nanoparticle stabilization
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DOI：
10.1039/c2cy20683h
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发表时间：
2013-02
影响因子：
5
通讯作者：
E. Rafter;T. Gutmann;F. Löw;G. Buntkowsky;K. Philippot;B. Chaudret;P. V. Leeuwen
中科院分区：
文献类型：
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作者：
E. Rafter;T. Gutmann;F. Löw;G. Buntkowsky;K. Philippot;B. Chaudret;P. V. Leeuwen
报道了以仲膦氧化物(SPO)为配体合成纳米Ru(RuNPs)的方法。这些易于获得的配体可以形成尺寸在1-2 nm范围内的小纳米颗粒，在TOF高达2700molh−1的情况下显示出高效率的芳烃加氢反应。
The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1–2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h−1.