BIOSYNTHESIS OF EPOXYDON AND RELATED COMPOUNDS BY PHYLLOSTICTA SP
BIOSYNTHESIS OF EPOXYDON AND RELATED COMPOUNDS BY PHYLLOSTICTA SP
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DOI：
10.1080/00021369.1975.10861599
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发表时间：
1975-01-01
期刊：
影响因子：
--
通讯作者：
SAKAMURA, S
中科院分区：
文献类型：
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作者：
NABETA, K;ICHIHARA, A;SAKAMURA, S
叶点霉属产生的epoxydon Ⅰ的四酮化合物来源。用~（13）C-和~（13）C-乙酸酯标记环氧化合物，通过~（13）C NMR测定，建立了一种新的标记环氧化合物的方法。通过将环氧菌酮暴露于培养液中，也证实了环氧菌酮氯化形成非酶促化合物IV、V和VI的机理。
The tetraketide origin of epoxydon I produced byPhyllostictasp. is established by13C NMR measurement on labelled epoxydons obtained from 1-13C- and 2-13C-acetate. The chlorinating mechanism of epoxydon to form non-enzymatically compound IV, V and VI was also confirmed by exposing epoxydon to the culture broth.