Use of n-pentenyl glycosides as precursors to various spacer functionalities
Use of n-pentenyl glycosides as precursors to various spacer functionalities
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DOI：
10.1021/jo9909554
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发表时间：
2000-02-25
影响因子：
3.6
通讯作者：
Fraser-Reid, B
中科院分区：
文献类型：
--
作者：
Buskas, T;Söderberg, E;Fraser-Reid, B
戊-4-烯基β-D-吡喃葡萄糖苷及其全乙酰化和全苄基化衍生物被证明是用于制备多种间隔基官能团的优异底物。这样得到的间隔衍生物是有前途的基板，用于制备试剂，如neo-glycoconjugates，胶束，和液晶相，这是感兴趣的研究各种生物和生理现象的碳水化合物。
Pent-4-enyl beta-D-glucopyranoside and its peracetylated and perbenzylated derivatives are shown to be excellent substrates for preparation of a wide variety of spacer functionalities. The spacer derivatives so obtained are promising substrates for preparing agents such as neo-glycoconjugates, micelles, and liquid crystalline phases, which are of interest for studying various biological and physiological phenomena of carbohydrates.