Trimethylsilyl Chloride PromotedSelective Desulfurization of Thiocarbonyls to Carbonyls with HydrogenPeroxide
Trimethylsilyl Chloride PromotedSelective Desulfurization of Thiocarbonyls to Carbonyls with HydrogenPeroxide
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DOI：
10.1055/s-0030-1258283
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发表时间：
2010-12
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影响因子：
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通讯作者：
K. Bahrami;M. Khodaei;Maryam Tajik
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文献类型：
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作者：
K. Bahrami;M. Khodaei;Maryam Tajik
在过氧化氢和三甲基硅氯存在下，硫代羰基脱硫为相应的羰基。该反应安全、操作简单、一般，反应时间短，产率高，无副反应，具有良好的区域选择性，是一种有吸引力的、环保的硫代羰基脱硫替代方法。
In the presence of hydrogen peroxide and trimethylsilyl chloride,thiocarbonyls desulfurize to the corresponding carbonyls. The safe,operationally simple, general reaction gives excellent yields inshort reaction times with no side reactions and excellent regioselectivity,which makes this process an attractive, environmentally benign alternativefor the desulfurization of thiocarbonyls.