Influence of operation conditions on direct NaBH4/H2O2 fuel cell performance

Influence of operation conditions on direct NaBH4/H2O2 fuel cell performance
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DOI:
10.1016/j.ijhydene.2009.04.020
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发表时间:
2010-04
影响因子:
7.2
通讯作者:
Wu Haijun;W. Cheng;L. Zhixiang;Mao Zongqiang
Wu Haijun;W. Cheng;L. Zhixiang;Mao Zongqiang
中科院分区:
工程技术2区
文献类型:
--
作者:
Wu Haijun;W. Cheng;L. Zhixiang;Mao Zongqiang

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Although hydrogen fuel cells have attracted so much attentions in these years because of the application prospect in electric vehicles, some obstacles have not been solved yet, among which hydrogen storage is one of the biggest. Direct borohydride fuel cell (DBFC) is another choice without hydrogen storage problem because borohydride is used as reactant directly in the fuel cell. In this paper, DBFC performance under different operation conditions was studied including electrolyte membrane type, operation temperature, borohydride concentration, supporting electrolyte and oxidant. Results showed that, with Pt/C and MnO2as anode and cathode electrocatalyst, respectively, Nafion®117 membrane as electrolyte, 1.0M, 3.0M and 6.0M NaBH4and H2O2solution in NaOH as reactant solution, 80°C operation, the peak power density could reach 130mW/cm2.