Reduction of Acetophenones UsingBorohydride Exchange Resins (BER) and a BER-Lithium Salt System

Reduction of Acetophenones UsingBorohydride Exchange Resins (BER) and a BER-Lithium Salt System
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使用硼氢化物交换树脂 (BER) 和 BER-锂盐系统还原苯乙酮

DOI:
10.1055/s-0029-1217040
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发表时间:
2009
期刊:
Synthesis
影响因子:
--
通讯作者:
José Afrânio Brenelli
José Afrânio Brenelli
中科院分区:
--
文献类型:
--
作者:
J. Fernandes;M. C. D. Souza;E. C. S. Brenelli;José Afrânio Brenelli

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用硼氢化物型聚苯乙烯-二乙烯基苯阴离子交换树脂进行苯乙酮的硼氢化物还原。通过添加LiNO 3、LiCl、LiBr或LiI,在不降低产率的情况下实现了高产率,并且反应速率显著增加。
Borohydride reduction of acetophenones was carried out with the borohydride-form of an anion exchange polystyrene-divinylbenzene resin. High yields were achieved and reaction rates were significantly increased by the addition of LiNO 3 , LiCl, LiBr or LiI without decreasing yield.