Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes
Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes
复制标题
通过阳离子铱酰胺络合物的金属-配体合作进行Si-H键的杂解断裂和醛的氢化硅烷化
DOI：
10.1039/d2dt01733d
复制
发表时间：
2022
影响因子：
4
通讯作者：
Sato Kazuhiko
中科院分区：
文献类型：
--
作者：
Iizuka Kosuke;Nakajima Yumiko;Sato Kazuhiko
硅-氢键的异裂是通过金属-配体的阳离子铱胺配合物来实现的。将该反应应用于苯甲醛及其衍生物的催化硅氢化反应，得到了相应的硅氢化产物，收率中等至较高。
Heterolytic cleavage of a Si–H bond was achieved mediated by a metal–ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields.