Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification
Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification
复制标题
DOI：
10.1039/d1cc03362j
复制
发表时间：
2021-07-22
影响因子：
4.9
通讯作者：
Miura, Masahiro
中科院分区：
文献类型：
--
作者：
Kato, Moena;Ghosh, Koushik;Miura, Masahiro
报道了采用碳酸亚乙烯酯作为乙醇当量的铑催化的直接甲酰甲基化反应。所开发的催化系统进一步用于无氧化剂生产酯并释放氢气。进行了一些对照实验来阐明反应机理。
A rhodium-catalysed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent is reported. The developed catalytic system is further utilised for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments are conducted to elucidate the reaction mechanism.