Novel mechanism for the modification of Al2O3-based inclusions in ultra-low carbon Al-killed steel considering the effects of magnesium and calcium

Novel mechanism for the modification of Al2O3-based inclusions in ultra-low carbon Al-killed steel considering the effects of magnesium and calcium
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考虑镁和钙影响的超低碳铝镇静钢中Al2O3系夹杂物变质新机制

DOI:
10.1007/s12613-018-1571-1
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发表时间:
2018-03
影响因子:
4.8
通讯作者:
Mei Ya guang
Mei Ya guang
中科院分区:
材料科学2区
文献类型:
--
作者:
Guo Jing;Cheng Shu sen;Guo Han jie;Mei Ya guang

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许多研究者对钢中夹杂物的变质机理进行了探索,以提高钢中非金属夹杂物的变质效果。采用不同Mg、Ca含量的超低碳铝镇静钢进行了两种钢液夹杂物变性工业试验,以验证炉外精炼过程中Ca、Mg含量对Al 2 O3基夹杂物变性机理的影响。结果表明,加入适量的Ca可使Al 2 O3基夹杂物变质为液态铝酸钙或多元夹杂物。此外,钢液中的[Mg]可进一步还原液态铝酸钙中的CaO,促使其演变为CaO-MgO-Al 2 O3多元夹杂物。热力学分析表明,当液态铝酸钙中MgO含量小于3wt%,温度高于1843 K时,[Mg]与CaO发生反应。
Many researchers have explored the inclusion modification mechanism to improve non-metallic inclusion modifications in steelmaking. In this study, two types of industrial trials on inclusion modifications in liquid steel were conducted using ultra-low-carbon Al-killed steel with different Mg and Ca contents to verify the effects of Ca and Mg contents on the modification mechanism of Al2O3-based inclusions during secondary refining. The results showed that Al2O3-based inclusions can be modified into liquid calcium aluminate or a multi-component inclusion with the addition of a suitable amount of Ca. In addition, [Mg] in liquid steel can further reduce CaO in liquid calcium aluminate to drive its evolution into CaO–MgO–Al2O3multi-component inclusions. Thermodynamic analysis confirmed that the reaction between [Mg] and CaO in liquid calcium aluminate occurs when the MgO content of liquid calcium aluminate is less than 3wt% and the temperature is higher than 1843 K.
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