Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources.
Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources.
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DOI：
10.1021/jacs.5b05513
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发表时间：
2015-07
影响因子：
15
通讯作者：
Xueqiang Wang;M. Nakajima;R. Martín
中科院分区：
文献类型：
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作者：
Xueqiang Wang;M. Nakajima;R. Martín
描述了一种温和且用户友好的镍催化炔烃与 CO2 (1 bar) 的区域选择性加氢羧化反应。该方案的特点是范围广，同时不需要敏感的有机金属物质，并且使用简单的醇作为质子源，具有前所未有的区域选择性模式。
A mild and user-friendly Ni-catalyzed regioselective hydrocarboxylation of alkynes with CO2 (1 bar) is described. This protocol is characterized by a wide scope while obviating the need for sensitive organometallic species and by an unprecedented regioselectivity pattern using simple alcohols as proton sources.