Asymmetric catalytic addition of diorganozinc reagents to imines:: Scope and application
Asymmetric catalytic addition of diorganozinc reagents to imines:: Scope and application
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DOI：
10.1351/pac200577071259
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发表时间：
2005-07-01
影响因子：
1.8
通讯作者：
Legault, C
中科院分区：
文献类型：
--
作者：
Charette, AB;Boezio, AA;Legault, C
在Me-DuPHOS一氧化物配体（BozPHOS）存在下，铜催化的二有机锌加成反应具有很高的对映体控制度.反应的范围进行了描述，以及我们的努力，以确定负责高不对称诱导的对映体活性金属络合物的性质。
The copper-catalyzed diorganozinc addition to N-diphenylphosphinoylimines was shown to proceed with a very high degree of enantiocontrol if the reaction was run in the presence of Me-DuPHOS monoxide ligand (BozPHOS). The scope of the reaction is described as well as our efforts to identify the nature of the enantioactive metal complex responsible for the high asymmetric induction.