Novel synthesis of ZnPc/TiO2 composite particles and carbon dioxide photo-catalytic reduction efficiency study under simulated solar radiation conditions
Novel synthesis of ZnPc/TiO2 composite particles and carbon dioxide photo-catalytic reduction efficiency study under simulated solar radiation conditions
复制标题
ZnPc/TiO2复合颗粒的新型合成及模拟太阳辐射条件下二氧化碳光催化还原效率研究
DOI:
10.1016/j.colsurfa.2012.06.010
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发表时间:
2012-09-05
影响因子:
5.2
通讯作者:
Zou Haikui
中科院分区:
文献类型:
--
作者:
Wang Qian;Wu Wei;Zou Haikui
In this paper, zinc phthalocyanine (ZnPc) and ZnPc/TiO2 composite particles were novelly prepared by microwave and microwave-hydrothermal methods, respectively. The products were characterized by scanning electron microscopy, transmission electron microscopy, UV-vis spectroscopy, X-ray diffractometry, infrared spectrophotometry and thermogravimetry analysis. IR spectra and TG analysis prove the incorporation of ZnPc with TiO2. Carbon dioxide was photo-catalytically reduced to produce methanol in an aqueous solution using simulated solar light irradiation. Compared with the pure TiO2 particles, the light absorption range of composite particles got to visible area and the CO2 photo-reduction capability was greatly enhanced, for which the methanol yield reached 248.06 mu mol/g cat. (C) 2012 Elsevier B.V. All rights reserved.