Large decanuclear calcium and strontium hydride clusters.
Large decanuclear calcium and strontium hydride clusters.
复制标题
DOI:
10.1039/d0cc04330c
复制
发表时间:
2020-07
影响因子:
4.9
通讯作者:
Johannes Martin;J. Eyselein;J. Langer;Holger Elsen;S. Harder
中科院分区:
文献类型:
--
作者:
Johannes Martin;J. Eyselein;J. Langer;Holger Elsen;S. Harder
Two large decanuclear hydride clusters of the general formula Ae10H16[N(R)R']4·(PMDTA)2 (Ae = Ca, Sr) were isolated. Both derivatives feature a [Ae10H16]4+ core, consisting of two edge shared metal octahedra with interstitial hydrides, while the other hydrides cap triangular faces.