Interconnected carbon-decorated Tio2 nanocrystals with enhanced lithium storage performance

Interconnected carbon-decorated Tio2 nanocrystals with enhanced lithium storage performance
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DOI:
10.1016/j.elecom.2013.12.028
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发表时间:
2014-03
影响因子:
5.4
通讯作者:
Yuanyuan Zhou;Songhun Yoon
Yuanyuan Zhou;Songhun Yoon
中科院分区:
工程技术3区
文献类型:
--
作者:
Yuanyuan Zhou;Songhun Yoon

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采用一种新的直接法制备了碳修饰的纳米TiO2。所制备的复合材料表现出互连的10 nm的TiO2纳米晶的形态与均匀的碳覆盖。作为锂离子电池负极,其具有184 mAh g− 1的高可逆容量和87.4%的初始库仑效率,优异的倍率性能和稳定的循环寿命,这归因于超细颗粒尺寸,均匀的碳涂层和高制备温度。
A novel direct preparation method was developed to prepare interconnected carbon-decorated TiO2nanocrystals. The as-prepared composite exhibited a morphology of interconnected 10 nm TiO2nanocrystals with uniform carbon coverage. As anode in lithium ion batteries, high reversible capacity of 184 mAh g− 1with 87.4% initial coulomb efficiency, outstanding rate performance and stable cycle life were observed, which was attributed to ultrafine particle size, uniform carbon coating and high preparation temperature.