THE ELECTRIFIED LIQUID-LIQUID INTERFACE
THE ELECTRIFIED LIQUID-LIQUID INTERFACE
复制标题
DOI：
10.1002/9780470431917.ch4
复制
发表时间：
2009-02
影响因子：
--
通讯作者：
R. Dryfe
中科院分区：
文献类型：
--
作者：
R. Dryfe
带电界面继续在凝聚相物理化学中发挥核心作用。在过去的几十年里，我们对这些界面的理解在接近分子的尺度上取得了巨大的进步，对于某些系统来说，也接近于原子。在类似的时期内，我们对液-液界面的理解也有了重大发展。然而，如果没有像扫描探针显微镜这样高分辨率的界面结构实验探头，就必须发展其他的理论和实验方法来建立一个框架来理解这种界面的结构和动力学。本章评价了液-液界面理解的最新进展，尤其集中在不相容的电解质溶液之间的界面。
Electrified interfaces continue to play a central role in condensed-phase physical chemistry. The last couple of decades have seen enormous strides in our understanding of these interfaces at scales approaching the molecular and, for certain systems, the atomic. Over a similar period, there have also been significant developments in our understanding of the liquid–liquid interface. However, without the benefit of such high-resolution experimental probes of interfacial structure as scanning probe microscopy, other theoretical and experimental methods must be developed to build a framework to understand the structure and dynamics of this interface. This chapter assesses the recent advances in the understanding of the liquid–liquid interface, concentrating particularly on interfaces between immiscible electrolyte solutions.