DETERMINATION OF MICELLE STRUCTURE AND CHARGE BY NEUTRON SMALL-ANGLE SCATTERING

DETERMINATION OF MICELLE STRUCTURE AND CHARGE BY NEUTRON SMALL-ANGLE SCATTERING
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DOI:
10.1007/bf01421709
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发表时间:
1983-01-01
影响因子:
2.4
通讯作者:
PENFOLD, J
PENFOLD, J
中科院分区:
化学4区
文献类型:
--
作者:
HAYTER, JB;PENFOLD, J

文献摘要

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我们提出了一个通用的方法来确定球形离子胶束的结构和电荷,使用中子小角散射。胶束溶液在胶束相中可以具有任何浓度。该方法的一部分是基于单分散球形胶束之间的颗粒间的相关性的分析计算,我们讨论了一些详细的理论,以证明其应用于多分散球形颗粒。几个阳离子和阴离子胶束系统的实验结果。
We present a general method of determining the structure and charge of globular ionic micelles, using neutron small-angle scattering. The micellar solutions may have any concentration within the micellar phase. The method is based in part on an analytic calculation of the interparticle correlations between monodisperse spherical micelles, and we discuss the theory in some detail to justify its application to polydisperse globular particles. Experimental results are presented for several cationic and anionic micellar systems.