An X-Ray Analysis of the Orientational Disorder of N-Methylphenazinium-TCNQ

An X-Ray Analysis of the Orientational Disorder of N-Methylphenazinium-TCNQ
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N-甲基吩嗪鎓-TCNQ 取向紊乱的 X 射线分析

DOI:
10.1246/bcsj.48.1373
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发表时间:
1975
影响因子:
4
通讯作者:
H. Kobayashi
H. Kobayashi
中科院分区:
化学3区
文献类型:
--
作者:
H. Kobayashi

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The X-ray diffraction patterns of NMP-TCNQ show diffuse streaks along the c* direction. The analysis of the intensities of these streaks revealed that the orientation of NMP is one-dimensionally disordered along the c axis. The structure obtained indicates that the potential exerting on an electron moving in a column of TCNQ is not random, but can be expressed by a periodic function; this implies that NMP-TCNQ, can not be regarded as a disordered one-dimensional conductor. The periodicity of the potential means that the one-dimensional energy band must be filled.