Isocorroles: Novel Tetrapyrrolic Macrocycles

Isocorroles: Novel Tetrapyrrolic Macrocycles
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异咔啉:新型四吡咯大环化合物

DOI:
10.1002/anie.199013901
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发表时间:
1990
期刊:
影响因子:
--
通讯作者:
E. Vogel
E. Vogel
中科院分区:
--
文献类型:
--
作者:
S. Will;A. Rahbar;H. Schmickler;J. Lex;E. Vogel

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卟啉衍生物的环收缩产生异可洛衍生物,其环骨架偏离平面性比可洛更显著。然而,根据光谱研究结果,该衍生物是芳香族化合物。1和3分别是母体化合物可罗和异可罗。
The ring contraction of a porphycene derivative yields an isocorrole derivative whose ring skeleton deviates significantly more from planarity than that of corrole. According to spectroscopic findings, however, the derivative is an aromatic compound. 1 and 3 are the parent compounds corrole and isocorrole, respectively.