Generation of Alkyl Radicals from 1-Oxidoalkylidenechromium(0) Complexes by Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Olefins
Generation of Alkyl Radicals from 1-Oxidoalkylidenechromium(0) Complexes by Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Olefins
复制标题
2-吡啶甲酸锰(III)氧化1-氧化亚烷基铬(0)配合物生成烷基自由基及其与烯烃的反应
DOI：
10.1246/cl.1993.1269
复制
发表时间：
1993
影响因子：
1.6
通讯作者：
H. Sakurai
中科院分区：
文献类型：
--
作者：
K. Narasaka*;H. Sakurai
由相应的碳负离子和六羰基铬(0)生成的四甲基铵五羰基(1-氧代亚烷基)铬(0)与2-吡啶甲酸锰(III)氧化生成碳心自由基，与各种烯烃反应生成分子间加成产物。
Tetramethylammonium pentacarbonyl(1-oxidoalkylidene)chromium(0) complexes, prepared from the corresponding carbanion and hexacarbonylchromium(0), are oxidized with manganese(III) 2-pyridinecarboxylate to generate carbon-centered radicals which react with various olefins giving the intermolecular addition products.