Cover Feature: Effect of “X” Ligands on the Photocatalytic Reduction of CO 2 to CO with Re(pyridylNHC-CF 3 )(CO) 3 X Complexes (Eur. J. Inorg. Chem. 19/2020)
Cover Feature: Effect of “X” Ligands on the Photocatalytic Reduction of CO 2 to CO with Re(pyridylNHC-CF 3 )(CO) 3 X Complexes (Eur. J. Inorg. Chem. 19/2020)
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封面专题：-X-配体对 Re(pyridylNHC-CF 3 )(CO) 3 X 配合物光催化还原 CO 2 为 CO 的影响 (Eur. J. Inorg. Chem. 19/2020)
DOI：
10.1002/ejic.202000421
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发表时间：
2020
影响因子：
2.3
通讯作者：
Delcamp, Jared H.
中科院分区：
文献类型：
--
作者：
Shirley, Hunter;Sexton, Thomas More;Liyanage, Nalaka P.;Palmer, C. Zachary;McNamara, Louis E.;Hammer, Nathan I.;Tschumper, Gregory S.;Delcamp, Jared H.
封面特征显示了“X”配体对通过一系列吡啶基N-杂环卡宾-三羰基络合物将CO2还原为CO的光催化剂的性能的影响。这些催化剂显示出令人印象深刻的速度和耐久性，在这个反应后，明智的“X”配体的选择。深入研究这些配体的理论离解能和光物理性质，得到了一种很有前途的方法，用于预测这些吡啶基NHC体系在CO 2还原反应中的速率和耐久性指标，并有可能将这种分析扩展到其他配体框架和金属。更多信息可以在JH Delcamp等人的论文全文中找到。
The Cover Feature shows the impact of an “X” ligand on the performance of photocatalysts reducing CO 2 to CO via a series of pyridyl N-heterocyclic carbene rhenium tricarbonyl complexes. These catalysts show impressive rate and durability in this reaction upon judicious “X” ligand selection. An in-depth look into the theoretical dissociation energies and photophysical properties of these ligands has led to a promising method for predicting rate and durability metrics in the CO 2 reduction reaction for these pyridyl NHC systems, with the potential to expand this analysis to other ligand frameworks and metals. More information can be found in the Full Paper by JH Delcamp et al.