Rate acceleration of Diels-Alder reactions utilizing a fluorous micellar system in water
Rate acceleration of Diels-Alder reactions utilizing a fluorous micellar system in water
复制标题
利用水中氟胶束系统加速狄尔斯-阿尔德反应
DOI：
10.1016/j.electacta.2011.02.087
复制
发表时间：
2011
影响因子：
6.6
通讯作者：
Kazuhiro Chiba
中科院分区：
文献类型：
--
作者：
Kohsuke Nishimoto;Yohei Okada;Kazuhiro Chiba
在水中的氟胶束系统已被创建，以产生这些介质之间的大的界面面积，保留基板，有效地促进分子间的狄尔斯-阿尔德反应，由于从两种介质的排斥效应。由于LiFOS不仅起表面活性剂的作用，而且还起支持电解质的作用，因此可以引入电化学方法来评估速率加速效应。氟胶束的粒度分布的测量清楚地支持这些评价。
A fluorous micellar system in water has been created to produce a large interfacial area between these media that retains substrates, effectively facilitating intermolecular Diels–Alder reactions due to repulsion effects from both media. Because LiFOS functioned not only as a surfactant but also as a supporting electrolyte, an electrochemical approach could be introduced to evaluate the rate acceleration effects. The measurement of the particle size distribution of the fluorous micelles clearly supported these evaluations.