Flow Photochemistry of Azosulfones: Application of "Sunflow" Reactors
Flow Photochemistry of Azosulfones: Application of "Sunflow" Reactors
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DOI：
10.1002/cptc.201800125
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发表时间：
2018-10-01
期刊：
影响因子：
3.7
通讯作者：
Opatz, Till
中科院分区：
文献类型：
--
作者：
da Silva Junior, Paulo Eliandro;Amin, Hawraz I. M.;Opatz, Till
芳偶氮砜在不需要任何额外催化剂的情况下，作为光活性前体在可见光反应中已被证实。在三个不同的地理位置（德国、意大利和巴西），在一个简单的太阳能微毛细管反应器中进行了各种（杂）芳香底物和异腈的芳基化。起始底物转化率高，反应时间短。
Arylazo sulfones have been established as photoactive precursors in visible-light photoreactions without any additional catalysts. The arylation of various (hetero) aromatic substrates and isonitriles was carried in a simple solar microcapillary reactor in three different geographical locations (Germany, Italy and Brazil). High conversion of the starting substrates as well as short reaction times were observed.