Preparation of anion exchange membrane by amination of chlorinated polypropylene and ethylenediamine and its properties
Preparation of anion exchange membrane by amination of chlorinated polypropylene and ethylenediamine and its properties
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DOI：
10.1002/app.31344
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发表时间：
2010-02
影响因子：
3
通讯作者：
Joo-Hee Hong;Sung-Kyu Hong
中科院分区：
文献类型：
--
作者：
Joo-Hee Hong;Sung-Kyu Hong
以氯化聚丙烯(CPP)和乙二胺(EDA)为原料，采用低温胺化法制备了阴离子交换膜，并对膜的物理性能和电化学性质进行了研究。氨化度分别为46.05、47.07、50.56和56.58。随着胺化程度的增加，CPP-EDA膜的吸水率分别为0.153、0.243、0.309和0.410 g/g干膜。该膜的离子交换容量为0.557-1.498 mequiv/g干膜，固定离子浓度为4.198-5.114 mequiv/g H2O。吸水率最高时，CPP-EDA膜的离子电导率最高。CPP-EDA膜的渗透系数在0.475×10−2~0.999×10−2 S/cm之间。《威利期刊》公司，《应用波利姆科学》，2010
An anion exchange membrane was prepared by amination of chlorinated polypropylene (CPP) and ethylenediamine (EDA) at a low temperature and was investigated with respect to not only its physical properties but also its electrochemical properties. The degrees of amination were 46.05, 47.07, 50.56, and 56.58% at 30, 40, 50, and 55°, respectively. The CPP membrane had no water uptake, whereas, that of the CPP-EDA membrane was 0.153, 0.243, 0.309, and 0.410 g of H2O/g of dry membrane, respectively, with increasing amination. The CPP-EDA membranes possessed an ion exchange capacity in the range 0.557–1.498 mequiv/g of dry membrane and a fixed ion concentration in the range 4.198–5.114 mequiv/g of H2O. The ionic conductivity of the CPP-EDA membrane was highest when the water uptake was highest. Those of the CPP-EDA membrane were in the range 0.475 × 10−2–0.999 × 10−2 S/cm. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010