Transition-metal-catalyzed synthesis of organosulfur compounds
Transition-metal-catalyzed synthesis of organosulfur compounds
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DOI：
10.1351/pac200880050993
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发表时间：
2008-05-01
影响因子：
1.8
通讯作者：
Yamaguchi, Masahiko
中科院分区：
文献类型：
--
作者：
Arisawa, Mieko;Yamaguchi, Masahiko
有机硫络合物是合成有机硫化合物的有效催化剂。它们催化有机硫基与不饱和化合物的加成反应、C-H与有机硫基的取代反应和单键歧化反应。它们裂解S-S键，将有机硫基转移到各种有机和无机分子上，包括炔、烯、二硫化物、硫、异腈、亚胺、二膦、硫代膦、氢、1-烷基硫代-1-炔、硫代酯和烯丙基硫化物。
Rhodium complexes are efficient catalysts for the synthesis of organosulfur compounds. They catalyze the addition reaction of organosulfur groups to unsaturated compounds, the substitution of C-H with organosulfur groups, and single-bond metathesis reactions. They cleave S-S bonds and transfer the organosulfur groups to various organic and inorganic molecules, including alkynes, allenes, disulfides, sulfur, isonitriles, imines, diphosphines, thiophosphinites, hydrogen, 1-alkylthio-1-alkynes, thioesters, and allyl sulfides.