Controllable Syntheses of MOF-Derived Materials
Controllable Syntheses of MOF-Derived Materials
复制标题
MOF 衍生材料的可控合成
DOI：
10.1002/chem.201705415
复制
发表时间：
2018
期刊：
影响因子：
--
通讯作者：
Li Zuo Xi
中科院分区：
文献类型：
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作者：
Zou Kang Yu;Li Zuo Xi
金属有机骨架材料（MOFs）作为一类重要的多孔无机-有机杂化材料，具有优异的物理化学特性，可作为多功能前驱体用于制备功能性MOFs衍生材料。然而，在合成过程中有很多复杂的因素，这远远没有达到有效控制MOF衍生材料的性质（如组成，形貌和表面积）的目标。因此，迫切需要开发用于MOF衍生材料的可控合成的常规方案和概念。本文主要根据近年来的文献报道，对影响MOF衍生材料制备的复杂因素进行了总结和分析，为合理设计和合成MOF衍生材料提供了新的思路。
Metal–organic frameworks (MOFs), as an important kind of porous inorganic‐organic hybrid materials with inherent outstanding physicochemistry characteristics, can be widely applied as versatile precursors for the facile preparation of functional MOF‐derived materials. However, there are plenty of sophisticated factors during the synthetic process, which is far from reaching the goal of effectively controlling the nature of MOF‐derived materials (such as the composition, morphology and surface area). Therefore, it is urgently necessary to develop regular protocols and concepts for controllable syntheses of MOF‐derived materials. In this minireview, we mainly summarize and analyze complicated factors in the fabrication of MOF‐derived materials according to recently reported literatures, and this provides a new insight into the rational design and syntheses of MOF‐derived materials.