Stereospecific polymerization of benzyl α-(methoxymethyl)acrylate
Stereospecific polymerization of benzyl α-(methoxymethyl)acrylate
复制标题
α-(甲氧基甲基)丙烯酸苄酯的立体定向聚合
DOI：
10.1021/ma951664
复制
发表时间：
1996
期刊：
影响因子：
5.5
通讯作者：
Y. Okamoto
中科院分区：
文献类型：
--
作者：
S. Habaue;H. Yamada;Y. Okamoto
合成了一种新型单体α-（甲氧基甲基）丙烯酸苄酯，并对其自由基聚合和阴离子聚合的反应活性和聚合物的立体规整性进行了研究。用锂离子试剂进行阴离子聚合，无论溶剂的极性如何，都能获得高等规性的聚合物
A novel monomer, benzyl α-(methoxymethyl)acrylate was synthesized and its reactivity and the stereoregularity of obtained polymers in radical and anionic polymerizations were investigated. The anionic polymerization by lithium agents was found to provide a polymer with a high isotacticity regardless of the polarity of the solvent