Architectural formation of a conjugated bimetallic Pd(II) complex via oxidative complexation and a tetracyclic Pd(II) complex via self-assembling complexation.
Architectural formation of a conjugated bimetallic Pd(II) complex via oxidative complexation and a tetracyclic Pd(II) complex via self-assembling complexation.
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通过氧化络合形成共轭双金属 Pd(II) 络合物和通过自组装络合形成四环 Pd(II) 络合物。
DOI：
10.1039/b203726m
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发表时间：
2002
影响因子：
4.9
通讯作者：
T. Hirao
中科院分区：
文献类型：
--
作者：
T. Moriuchi;Masayuki Kamikawa;S. Bandoh;T. Hirao
通过 1,4-苯二胺与钯 (II) 络合物 [(L1)Pd(MeCN)] (H2L1 = N,N'-双(2-苯乙基)-2,6-吡啶二甲酰胺)在没有额外配体的情况下[(L1)Pd(MeCN)]被转化为酰胺桥联的大环四聚体[Pd(L1)]4。
The conjugated homobimetallic palladium(II) complex [(L1)Pd(qd)Pd(L1)] (qd = quinonediimine) was obtained in a one-pot reaction by the in-situ oxidative complexation of 1,4-phenylenediamine with the palladium(II) complex [(L1)Pd(MeCN)] (H2L1 = N,N'-bis(2-phenylethyl)-2,6-pyridinedicarboxamide) while in the absence of an additional ligand [(L1)Pd(MeCN)] was converted to the amide-bridged macrocyclic tetramer [Pd(L1)]4.