SECONDARY MOLD METABOLITES .13. FUNGAL PERYLENEQUINONES - PHLEICHROME, ISOPHLEICHROME, AND THEIR ENDOPEROXIDES

SECONDARY MOLD METABOLITES .13. FUNGAL PERYLENEQUINONES - PHLEICHROME, ISOPHLEICHROME, AND THEIR ENDOPEROXIDES
复制标题

DOI：
10.1039/p19850001387
复制
发表时间：
1985-01-01
期刊：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
影响因子：
--
通讯作者：
MERLINI, L
MERLINI, L
中科院分区：
其他
文献类型：
--
作者：
ARNONE, A;CAMARDA, L;MERLINI, L

文献摘要

被引文献

相似文献

螺旋形的真菌[草枝孢]色素已经异构化为等脉色素。两个苝醌的侧链碳的轴向手性和绝对构型已经建立。这两种化合物的光氧化立体专一地发生，产生它们的内过氧化物，其结构和立体化学结果来自它们的n.m.r.的详细分析。谱
The helix-shaped, fungal [Cladosporium phlei] pigment phleichrome has been isomerized to isophleichrome. The axial chirality and absolute configuration of the side-chain carbons of both perylenequinones have been established. Photo-oxidation of both compounds occurs stereospecifically to give their endoperoxides, whose structure and stereochemistry results from a detailed analysis of their n.m.r. spectra.