Benzene-Free Synthesis of Multisubstituted Catechol via Oxidative Dearomatic Reorganization
Benzene-Free Synthesis of Multisubstituted Catechol via Oxidative Dearomatic Reorganization
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DOI：
10.1021/acs.orglett.1c00071
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发表时间：
2021-02-09
期刊：
影响因子：
5.2
通讯作者：
Zhu, Shifa
中科院分区：
文献类型：
--
作者：
Cao, Tongxiang;Shi, Qiu;Zhu, Shifa
A benzene-free synthesis of multisubstituted catechol via an oxidative dearomatic reorganization is reported. This reaction tolerated a wide spectrum of functionalities, which could be applied in the synthesis of an electron-deficient arene-conjugated catechol that is difficult to access via biomimetic oxidative coupling. In addition, a diversification-oriented transformation that leveraged the versatile catechol afforded a series of functionality-rich products.
